CO2 as the Primary Driver of Climate Change During the Phanerozoic
A little while ago I watched a short lecture by R.B. Alley that did a marvelous job of explaining why geologists have overwhelmingly concluded that greenhouse gases (and in particular CO2) are the primary drivers of climate changes on geologic time scales. This presentation was given prior to the publication of Judd et al 2024,[1] so I thought it might be fun to show how his argument would be enhanced even more with the more recent data we now have about Phanerozoic temperature and CO2. But let me set the stage.
GMST is set by a balance between incoming absorb solar radiation (ASR) and outgoing longwave radiation (OLR). ASR is affected by changes in how much sunlight reaches the earth (solar variability), where and when sunlight reaches the earth (orbital cycles) and how much is reflected vs absorbed (albedo). Outside influences can also at least theoretically play a role in affecting process on earth (galactic cosmic rays) that could change how much incoming solar is absorbed. OLR is affected by the greenhouse effect (greenhouse gases and high altitude clouds). What geologists have discovered is that Earth's temperature history does not make sense if you try to explain it only with variability in ASR. We're far enough away from the Sun that it cannot heat the planet to the temperatures we experience, even if nearly all the solar energy the Earth receives is absorbed. Earth's temperature history only makes sense when allowing for changes on the OLR side of the energy balance equation. And this is not all that difficult to show.
ASR: Solar and Albedo-Related Influences
Solar Variability
We know that the Sun was only about 70% as bright as it is today when the Earth was formed. This is the basic physics of solar evolution we've understood since Carl Sagan, who did the relevant calculations. The Sun fuses hydrogen into helium, and as it does the density of the solar core increases, and so fusion must occur at a faster rate to balance gravity. Consequently, the Sun has been getting brighter with time, though this is only significant on long geologic time scales. In fact, TSI can be accurately calculated for any time in Earth's geologic history.[3]
However, the Earth is so far away from the Sun that even at the Sun's current brightness (1361 W/m^2) our planet should be a giant snowball. With a current value for Earth's albedo of 0.3, the Earth's effective temperature is currently about 255 K (-18°C), but the Sun's brightness was only about 972 W/m^2 when Earth was formed, so the Earth's effective temperature (assuming the same albedo) would have been 235K (-38°C) then. So if the Earth was governed solely by changes in TSI, we should have always been a giant snowball in space.
Albedo
The Earth today reflects about 30% of the sunlight it receives due largely to clouds and ice. Albedo is also a powerful positive feedback; warming temperatures decrease the surface area of ice. Since ice reflects more sunlight than bare ground and ocean water, the ice-albedo amplifies amplifies a warming signal. When the planet cools, ice advances, and the Earth reflects more and absorbs less. Once we get about 10-12°C colder than today, the ice-albedo feedback can push Earth into "snowball earth" conditions, with ice covering ocean water at or near the equator. This has happened a few times in the geologic past before the Phanerozoic. During these times Earth's albedo probably exceeded 0.5.
As I show in the graph below, even if we assume Earth's albedo is never higher than 0.35, Earth's temperature history on would have been in constant snowball earth conditions throughout its history, with temperatures increasing by about 20°C over the last 4.5 billion years and variability from albedo adding or subtracting a few °C throughout Earth's history.
I calculated TSI at Earth given solar evolution[3] and then plotted a range of effective temperatures on Earth for the last 4.5 billion years, assuming albedo values between 0.25 and 0.35. This of course is idealized, since an Earth with oceans at this temperature would freeze and push albedo above 0.5. I also show temperature given an impossibly low value for albedo equal to the albedo of the moon (0.11).
Clearly the above graph does not resemble Earth's actual temperature history at all. Throughout most of Earth's history, since we had a solid crust and oceans, the Earth has been warm enough to have liquid water at the surface. In fact, snowball earth episodes make up a very small fraction of Earth's temperature history, and even "ice ages" with polar ice caps take up much less geologic time than time without polar ice caps. The Earth has normally been much hotter than today, even though the Sun was much less bright than today in the geologic past. In fact, even assuming the albedo of the Moon (0.11), my idealized plot shows the maximum temperature would be about 271 K (about 17 K colder than current temperatures). And this is still cold enough for ice to expand and increase albedo to higher than today. In reality, given our oceans, it's physically impossible to have albedo this low on Earth. If the Earth's temperature were governed solely by the Sun and albedo, the prevailing climate conditions seen on Earth for the last 4.5 billion years would be impossible.Orbital Forcings
Cosmic Rays
OLR: Greenhouse Gases
If we include the greenhouse effect, however, we can explain why it is that the Earth has had liquid water at the surface for most of geologic history. With Judd et al 2024,[1] we now have pretty good evidence for both CO2 and GMST for the last 485 million years. CO2 cycles in an out of the climate system on geologic time scales through volcanism, which supply atmospheric CO2, and chemical weathering of rocks is slowly working to remove it as CO2 and H2O interacts with CaSiO3 to remove CO2 from the atmosphere. Living organisms also play a role here, since calcified organisms take up CO2 in the process of forming CaCO3 shells. When these organisms die, they sink to the bottom and their shells get subducted under subduction zones, where volcanoes may return the carbon to the atmosphere as CO2. Tectonic forces change the rates at which these processes occur, as does temperature. What's most important for climate here is that chemical weathering occurs at faster rates when climate is warmer, and so this is a stabilizing influence on climate (on time scales of a half million years). Chemical weathering increases when climate is warm, reducing CO2 concentrations, and it decreases when temperatures are cool, allowing CO2 to accumulate in the atmosphere. In effect, chemical weathering is a slow but steady negative feedback. When something perturbs the carbon cycle either towards warming or cooling, these processes work to cool warm periods and warm cool periods in Earth's history.
Nevertheless, perturbations of the carbon cycle by long-term and large scale eruptions at Large Igneous Provinces (as in the eruption of the Siberian Traps that largely caused the Great Dying) can disrupt the climate system faster than these stabilizing mechanisms can restore it. Biological process also play a large role affecting CO2 concentrations. Atmospheric CO2 levels in the Cambrian and Ordovician sometimes reached 2000 ppm or even 3200 ppm, but as land plants flourished cross the continents in the Devonian, CO2 levels began to drop and reached levels similar to current CO2 concentrations in the Carboniferous, and even lower in the early Permian. Below I show Judd's reconstruction of CO2 concentrations for the last 485 million years. This is the most accurate proxy record we have to date, though there are studies showing variability in CO2 on much shorter time scales that are not represented well on this graph.
The fascinating aspect of Judd's paper is that, even ignoring solar evolution for the last 485 million years, CO2 explains a great deal of Earth's temperature variability, where 2xCO2 correlates with ~7.7°C on geologic time scales with an r^2 of 0.52. CO2 is not the only factor controlling GMST, but it's a very important one.Conclusion
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| The GHE is Essentially the Difference Between Global Mean and Effective Temperature |
https://www.researchgate.net/publication/309791338_Nonlinear_climate_sensitivity_and_its_implications_for_future_greenhouse_warming
TSI = the solar constant at T
TSIp = the solar constant at present (1361 W/m^2)
T = time in the past from the age of the earth
To = the age of the earth (4567 million years)
ε = Surface emissivity
σ = Stefan Boltzmann Constant
https://pdfs.semanticscholar.org/d61d/0fbcb5828af1d434d1bd0282ed36e0f00d2a.pdf

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